Arsenic

Formula: As; CAS Registry Number: 7440-38-2

Ubiquitous toxic metalloid

Arsenic compounds were used as pesticides in agriculture and forestry until the 1980s and 2004, respectively. Moreover, several drugs are based on arsenic and it is used e.g. in electronic industry, metal alloys, and in the process of glass production.

Weathering, volcanic activities, and solution in waters, biological processes and anthropogenic activities may lead to emissions of arsenic. It is mobile in all environmental compartments and may circulate for a long time before settling in sediments.

Several arsenic compounds are highly toxic to humans and classified as carcinogenic, teratogenic and mutagenic

Toxicity has also been demonstrated for birds, aquatic and terrestrial organisms. Arsenic is accumulated by aquatic organisms (bioaccumulation). Biomagnification in the food web can not be ruled out.

Guidelines for Chemical Analysis: Determination of Arsenic and Selenium in Environmental Samples by ICP-MS after Hydride Formation

Specimen

Common spruce A major primary producer in semi-natural and anthropogenic affected ecosystems.
Pine A major primary producer in semi-natural and anthropogenic affected ecosystems.
Lombardy poplar A deciduous tree typical of ecosystems close to dense conurbations and an indicator for the characterisation of the immission situation during the vegetation period.
Beech As the most dominant deciduous tree species in Central Europe, it plays a significant role in most nearly natural and also anthropogenically influenced forest ecosystems up to an altitude of 1100 m.
Zebra mussel Common mussel species as invasive animal in rivers and lakes with high information level for water pollution
Bream Bioindicator in rivers and lakes
Common bladder wrack Common brown alga of the coastal areas of the North and Baltic Sea
Blue mussel One of the most important edible mussel species common in the North and Baltic Sea
Eelpout As the only viviparous fish in German nearshore waters, it is a bioindicator in nearshore coastal marine ecosystems.
Herring gull Inshore, the herring gull mainly feeds from the sea: upon fish, mussels, and crabs.
Suspended particulate matter Fine insoluble mineral or organic particles in the water phase

Sampling area

BR/NP Berchtesgaden The only high mountains national park in Germany and an area of the Limestone Alps with international relevance.
Saarländischer Verdichtungsraum Important, old-industrialised conurbation in Germany.
Bornhöveder Seengebiet Main watershed between the North- and Baltic Sea.
Rhein Longest river in Germany.
NP Bayerischer Wald The Bavarian Forest National Park is Germany's first national park.
NP Vorpommersche Boddenlandschaft National Park in the largest brackish water (Bodden) habitat of the world.
BR/NP Wattenmeere National park in the world largest connected sand and mud flats.
Elbe Fourth largest river area in Central Europe.
Dübener Heide Region in the chemical triangle of Central Germany.
NP Harz The Harz National Park is Germany's largest forest national park.
Solling Second highest and largest low mountain range in Northern Germany.
BR Pfälzerwald Germany's largest connected forest area in a range of low mountains.
Oberbayerisches Tertiärhügelland The Upper Bavarian Tertiary Uplands are a part of the Southern German Molasse Basin.
Donau Second largest river in Europe.

Sampling period

1985 - 2010

Extended information

Links to external information and legislation

Literature

  • Bewertungsmaßstäbe für Arsen in Böden, Grund- und Trinkwasser
    Schuhmacher-Wolz U., Schneider K., Klein D.
    Umweltbundesamt Forschungsbericht 206 61 201, 2007
    To Publication